Thermally Stable, Latent Olefin Metathesis Catalysts
نویسندگان
چکیده
منابع مشابه
Thermally Stable, Latent Olefin Metathesis Catalysts.
Highly thermally stable N-aryl,N-alkyl N-heterocyclic carbene (NHC) ruthenium catalysts were designed and synthesized for latent olefin metathesis. These catalysts showed excellent latent behavior toward metathesis reactions, whereby the complexes were inactive at ambient temperature and initiated at elevated temperatures, a challenging property to achieve with second generation catalysts. A st...
متن کاملWell-defined silica-supported olefin metathesis catalysts.
Two triethoxysilyl-functionalized N-heterocyclic carbene ligands have been synthesized and used to prepare the corresponding second-generation ruthenium olefin metathesis catalysts. These complexes were then grafted onto silica gel, and the resulting materials were efficient heterogeneous catalysts for a number of metathesis reactions. The solid-supported catalysts were shown to be recyclable o...
متن کاملOlefin Metathesis by Supported Metal Oxide Catalysts
The literature of olefin metathesis by heterogeneous supported catalysts, both industrial-type supported metal oxides (ReOx/Al2O3, ReOx/(SiO2−Al2O3), MoOx/SiO2, MoOx/Al2O3, MoOx/(SiO2−Al2O3), WOx/SiO2, and WOx/ (SiO2−Al2O3)) and supported organometallic complexes, is comprehensively reviewed. The focus of this Review is supported metal oxide catalysts, but the well-defined supported organometal...
متن کاملConsequences of the electronic tuning of latent ruthenium-based olefin metathesis catalysts on their reactivity
Two ruthenium olefin metathesis initiators featuring electronically modified quinoline-based chelating carbene ligands are introduced. Their reactivity in RCM and ROMP reactions was tested and the results were compared to those obtained with the parent unsubstituted compound. The studied complexes are very stable at high temperatures up to 140 °C. The placement of an electron-withdrawing functi...
متن کاملDiphenylamido Precursors to Bisalkoxide Molybdenum Olefin Metathesis Catalysts.
We have found that Mo(NAr)(CHR')(NPh(2))(2) (R' = t-Bu or CMe(2)Ph) and Mo(NAr')(CHCMe(2)Ph)(NPh(2))(2) (Ar = 2,6-i-Pr(2)C(6)H(3); Ar' = 2,6-Me(2)C(6)H(3)) can be prepared through addition of two equivalents of LiNPh(2) to Mo(NR″)(CHR')(OTf)(2)(dme) species (R″ = Ar or Ar' dme = 1,2-dimethoxyethane), although yields are low. A high yield route consists of addition of LiNPh(2) to bishexafluro-t-...
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ژورنال
عنوان ژورنال: Organometallics
سال: 2011
ISSN: 0276-7333,1520-6041
DOI: 10.1021/om200911e